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A new approach to 3,6‐disubstituted chiral piperazinones 6a, b and 7a, b from D‐glucosamine hydrochloride (1) or N‐Z‐D‐glucosamine (8) and L‐amino acid derivatives 2a, b or 9a, b is presented. Both final products and the intermediate pseudopeptides constitute valuable starting materials for the synthesis of peptidomimetics.
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Kolter et al. (1995) studied this question.
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