Time-of-flight drift mobility experiments have been carried out on poly(di-n-hexylsilylene) (PDHS) and poly(di-n-butylgermylene)(PDBG) over a wide range of temperature and electric field. A change in transport behavior in PDHS and PDBG associated with the conformational transitions which are responsible for the bathochromic shift in these polymers, is unambiguously demonstrated.
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Abkowitz et al. (1991) studied this question.
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