The photochemical reaction of C 60 with disilane 1 affords the adduct 2 as a bissilylated product. The unique redox properties of 2 are reported by means of differential pulse voltammetry. The compound 2 was characterized by NMR, IR, and UV−vis spectroscopies. Spectroscopic and theoretical investigation strongly support the 1,16-addition structure having C 2 symmetry which results from addition at the 1,16 positions in C 60 . The results are reasonably accounted for by the generation of a silyl radical which is responsible for the formation of 2 .
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Akasaka et al. (1998) studied this question.
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