The photochemical reaction of disilirane with C 60 in benzonitrile affords the adduct of disilirane and benzonitrile as a bis-silylated product. In this reaction, C 60 serves as a sensitizer. The results are reasonably accounted for by a novel metal-free bis-silylation of an unsaturated compound via a photoinduced electron-transfer process.
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Akasaka et al. (1999) studied this question.
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