We present the first synthesis of an N-heterocyclic carbene (NHC) rhodium catalyst immobilized to an amphiphilic, water-soluble block copolymer support. The resulting macroligand was applied in the hydroformylation of 1-octene under aqueous two-phase conditions in four consecutive cycles and showed high activity up to 2360 h - 1 (TOF).
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Zarka et al. (2004) studied this question.
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