Tailoring surface reaction pathways by self-assembling a trifluoromethyl-terminated molecular layer to enhance photocatalytic cellulose-to-syngas conversion in pure water

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A trifluoromethyl-terminated hole-selective self-assembling molecule-modified S-scheme heterojunction of ZnSe@TiO 2 has been designed and constructed for enhanced photocatalytic conversion of biomass to syngas by steering the catalytic pathway.