Ion and solvent transport in polythionine and polyvinylferrocene films have been monitored under transient conditions using the electrochemical quartz crystal microbalance. Film sources of required species are utilized before solution-phase sources. Potential gradients within the film influence ion motion, resulting in a diversity of transport rates which can give rise to transient permselectivity.
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Hillman et al. (1990) studied this question.
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