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Poly(4‐vinylphenylacetate‐co‐maleic anhydride) was synthesized by free‐radical initiation to yield a 1:1 copolymer over a 0.2‐0.8 mole fraction range of monomer feed in maleic anhydride. Evidence of 1:1 charge transfer complex between 4‐vinylphenylacetate and maleic anhydride was obtained in the UV region at 355 nm. The 13C NMR chemical shifts and 1H NMR integration data indicate that poly(4‐vinylphenylacetate‐co‐maleic anhydride) has an alternating and stereoregular structure. The molecular weight of poly(4‐vinylphenylacetate‐co‐maleic anhydride) was controlled by using specific solvents and initiator concentrations.
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Jones et al. (1986) studied this question.
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