Emerging Hexagonal Mo2C Nanosheet with (002) Facet Exposure and Cu Incorporation for Peroxymonosulfate Activation Toward Antibiotic Degradation

The catalyst with a special exposed active facet and multivalent element synergism is much desired for advanced oxidation progress (AOP) reaction. Herein, an emerging substrate, Cu-incorporated Mo 2 C, with an active (002) facet exposed was developed by one-step calcination to activate peroxymonosulfate (PMS) toward antibiotic degradation. Combining the multivalent Cu–Mo synergistic effect and Cu complexing interaction, Cu was incorporated onto the Mo 2 C surface to further enhance its antibiotic removal through PMS activation. Scanning electron microscopy (SEM) and transmission electron microscopy (TEM) measurements indicated the 5% Cu–Mo 2 C exhibited in the hexagonal nanosheet with Cu uniformly dispersed on the surface. Moreover, 5% Cu–Mo 2 C displayed excellent PMS activation which could fully degrade the tetracycline (TC) within 20 min, and the degradation rate was found to be at least 20 times higher than those of pure Mo 2 C, classical Fe 2 O 3 and Co 3 O 4, and Fenton reaction of 5% Cu–Mo 2 C. The results were found to be ascribed to enhanced electrical conductivity, multivalent Cu–Mo synergism, and increased generation of active radicals which contributed in the sequence SO 4 • – > •OH > O 2 •– . Surface chemical analysis combined with density functional theory (DFT) calculations confirmed that both Cu 2+ /Cu + and Mo 6+ /Mo 4+ /Mo 2+ redox cycles occurred on the (002) plane of Mo 2 C, which dominated more free electrons and mainly accounted for facilitating PMS activation. Meanwhile, systematically conditional experiments uncovered that the 5% Cu–Mo 2 C exhibited superb catalysis even under a wide pH and temperature, various natural polluted waters and coexisting ions, and long-time recycle. In addition, the as-prepared catalyst presented excellent adaptability for the degradation of different organic effluents originated from medical, dyeing, and beneficiation wastewaters. Considering its great performance, stability, and applicability, 5% Cu–Mo 2 C would be a capable candidate for PMS activation toward large-scale practical application in environmental remediation.