Hard-core uranium chemistry: The 3,5-dimethylpyrazolate anion can be activated by uranium(III) to form 4-ketimidopent-2-ene-2-imido (kipi3−) units, which are isoelectronic to acetylacetonate. Three related tetranuclear uranium cluster compounds were isolated (see picture), of which two are mixed valent.
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Rinehart et al. (2010) studied this question.
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