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The samarium complex Cp*2SmCH(SiMe3)2(Cp*= C5Me5), unlike the related alkyls Cp*2LnCH(SiMe3)3(Ln = Y, Nd), mediates the redistribution of hydrosilanes while being converted to trisamarium clusters, including Cp*6Sm3(µ-SiH3)(µ3-η1,η1,η2-SiH2-SiH2).
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Radu et al. (1996) studied this question.
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