The Au(I)-catalysed rearrangement of propargylic esters formed from an ynamide has been studied. The reaction is facile, and when conducted in the presence of a reactive indole nucleophile, leads to a cascade process whereby γ-indolyl α-acyloxyenamides are formed in good yield and excellent E-stereoselectivity. Original language English Pages (from-to) 2314-2316 Journal Chemical Communications Volume 49 Issue number 23 Early online date 7 Feb 2013 DOIs https://doi.org/10.1039/c3cc00273j Publication status Published - 2013
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Heffernan et al. (2013) studied this question.
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