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Recent developments of Markovnikov selective hydrofunctionalization of olefins are discussed. It is note that we realized hydrofunctionalization such as an intermolecular hydroalkoxylation, a hydrofluorination, and an intramolecular hydroamination with excellent functional group tolerance using cobalt complex, N-fluoropyridinium salt, and disiloxane. Mechanistically, this catalysis involves both carbon radical and carbocation intermediate.
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Shigehisa et al. (2015) studied this question.
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