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A simple and facile fluorous biphasic catalytic oxidation of alkenes and aldehydes with 1 atm of air and 2‐methylpropanal in the presence of the (β‐perfluoroalkylated tetraphenylporphyrin)cobalt complexes [Co{TPP(C8F17)4}] (Co2) has been demonstrated for the first time. This kind of β‐perfluoroalkylated tetraphenylporphyrin may be used in other catalytic applications because of its ready availability and unique properties. (© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2006)
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Liu et al. (2006) studied this question.
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