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The first acyclic diaminocarbene (ADC) featuring N - aryl groups, as well as two complexes containing this ligand, (ADC)RhCl(1,5- cis, cis -cyclooctadiene) and (ADC)RhCl(CO) 2, were synthesized and characterized. Insight into controlling conformational diversity in acyclic diaminocarbenes with N - aryl groups through judicious N substitution was also explored.
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Rosen et al. (2007) studied this question.
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