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January 1, 1997Journal of the Chemical Society Perkin Transactions 2

Applicability and mathematical verification of the reactivity–selectivity principle in the oxidation of thioanisoles by oxo(salen)manganese(V) complexes

Arunachalam Chellamani N. M. I. Alhaji Seenivasan Rajagopal

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Abstract

The second-order rate constants for the oxidation of various para-substituted thioanisoles with substituted oxo(salen)manganese(V) complexes have been measured spectrophotometrically in acetonitrile at 25 °C. Electron-withdrawing substituents in thioanisoles and electron-releasing substituents in oxo(salen)MnV complexes decrease the rate of oxidation. Correlation analyses show the presence of an inverse relationship between reactivity and selectivity in the reactions of various thioanisoles with a given oxo(salen)MnV complex and also in various oxo(salen)MnV complexes with a given thioanisole. Mathematical treatment of the results has also been carried out.

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Chellamani et al. (1997) studied this question.

synapsesocial.com/papers/6a963a9fda4ae31144f6921d https://doi.org/10.1039/a604602i

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