Phosphorus‐Modulation‐Triggered Surface Disorder in Titanium Dioxide Nanocrystals Enables Exceptional Sodium‐Storage Performance

Structural modulation and surface engineering have remarkable advantages for fast and efficient charge storage. Herein, we present a phosphorus modulation strategy which simultaneously realizes surface structural disorder with interior atomic‐level P‐doping to boost the Na+ storage kinetics of TiO2. It is found that the P‐modulated TiO2 nanocrystals exhibit a favourable electronic structure, and enhanced structural stability, Na+ transfer kinetics, as well as surface electrochemical reactivity, resulting in a genuine zero‐strain characteristic with only approximately 0.1 % volume variation during Na+ insertion/extraction, and exceptional Na+ storage performance including an ultrahigh rate capability of 210 mAh g−1 at 50 C and a strong long‐term cycling stability without significant capacity decay up to 5000 cycles at 30 C.