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Using the method of Edwards and Singh we calculate the mean square radius 〈R2〉 of the polyelectrolyte chain in solution containing counterions for the temperature greater than the Flory’s θ temperature. For the counterion density n we obtain: (a) 〈R2〉∝L2 when n→0, and (b) 〈R2〉∝L6/5 when n→∞. These results are in agreement with the Flory-type calculations and recent Monte Carlo simulations performed by Baumgärtner.
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Chen et al. (1987) studied this question.
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