Optical properties of structurally sorted single‐wall carbon nanotube ensembles

Using density gradient ultracentrifugation and isopycnic fractionation we structurally sort traditionally prepared single‐wall carbon nanotube suspensions, and show that fractions with photoluminescence (PL) quantum yields of over 1% can be isolated. Moreover, we find that traditionally prepared suspensions appear to be composed of a significant fraction of small nanotube aggregates which reduce the quantum yield of the ensembles by a factor of 5 with respect to the most photoluminescent fractions. In order to better understand the nature of the nonradiative decay processes that lead to lower ensemble PL quantum yields, nanotube ropes of diameter enriched tubes are made and compared with the aforementioned ensemble measurements. Changes in the optical properties are discussed in terms of energy transfer to metallic tubes, carbonaceous particles, and smaller band gap tubes. (© 2007 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim)