The one-dimensional gallium fluorophosphate Ga(HPO4)2F·H3N(CH2) 3NH3·2H2O 1 crystallises at room temperature from an aqueous mixture of Ga2O3, H3PO4, 1,3-diaminopropane, and HF; compound 1 converts to the three-dimensional microporous fluorophosphate ULM-3 on heating to 160 °C under hydrothermal conditions.
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Walton et al. (2000) studied this question.
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