A simple and efficient method has been developed for the switchable synthesis of directly linked meso-brominated Ni(II) porphyrin dimers through PIFA-BF3·Et2O mediated oxidative coupling. The respective syntheses of meso-meso or meso-β singly, doubly, and triply linked porphyrin dimers can be easily realized with the same reagent system.
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Feng et al. (2014) studied this question.
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