Cyclopentadienylidene was studied by laser flash photolysis (LFP) techniques. LFP of diazocyclopentadiene in acetic anhydride, acetaldehyde, acetone, dimethyl carbonate, ethyl acetate, acetonitrile, dimethyl sulfide and pyridine produces UV-visible active ylides. The first reports of the direct detection of carbene—anhydride, carbene-aldehyde, carbene-amide and carbene-carbonate ylides are presented. The spectra and the lifetimes of these ylides are reported.
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Platz et al. (1996) studied this question.
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