All articles of this category A two-step synthesis of benzylic triflones, based on the reaction of 2,4,6-trisubstituted phenyl halides 3a-f with the anion of ethyl (trifluoromethanesulfonyl)acetate 1 followed by a decarboxylation reaction, is reported. The structural assignments are supported by spectroscopic data. benzylic triflones - S N Ar - decarboxylation - sodium triflinate - nitration
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Goumont et al. (1997) studied this question.
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