A new polarographic method for determining complex‐stability constants is described. In solutions where the total metal‐ion concentration is equal to the ligand concentration, a relation has been found between the shift of the half‐wave potential and the degree of dissociation. The stability constants of some Cd2+ and Zn2+ complexes, determined by this method, are in agreement with those cited in the literature.
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Bernauer et al. (1958) studied this question.
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