An efficient perovskite solar cell with symmetrical Zn( ii ) phthalocyanine infiltrated buffering porous Al 2 O 3 as the hybrid interfacial hole-transporting layer

A new Zn(ii) phthalocyanine (Pc) based low bandgap HTM is introduced for perovskite solar cells. Steady state and time-resolved photoluminescence (PL) measurements indicated an evenly matched hole extraction efficiency between sym-HTPcH and spiro-OMeTAD. On account of the low film quality and resulting high recombination, Zn(ii) Pc normally cannot work as an effective HTM. We adopted insulating Al