The pseudobinary phase diagrams show the temperature and oxygen partial pressure required to synthesize non-stoichiometric (x = 1.98 - 2.03), (x = 2.0 - 2.06) and (x = 2.0 - 2.16), the melting points (1090, 1176 and ) and the various decomposition products.
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Hauck et al. (1996) studied this question.
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