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It is shown theoretically that the recently observed spontaneous ordering of III-V alloys that yields alternate monolayer (111) superlattices provides the opportunity for achieving infrared band gaps in systems such as (InAs)1(InSb)1 and (GaSb)1(InSb)1. A substantial reduction in the direct band gap is predicted to result from the L-point folding that repel the Γ band-edge states.
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Wei et al. (1991) studied this question.
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