Abstract (1R, 2R, 4R)‐2‐endo‐Cyano‐7‐oxabicyclo[2.2.1]hept‐5‐en‐2‐yl acetate ((−)‐7) has been transformed into the all‐cis‐configurated 4L‐4,5,6/0‐trihydroxycyclohex‐2‐en‐1‐one derivatives (−)‐12 and (−)‐19. (−)‐Conduritol C ((−)‐3) was derived in a stereospecific manner from (−)‐12.
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Drian et al. (1989) studied this question.
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