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PC bonds mimic CC bonds in the radical-initiated copolymerization of a phosphaalkene 1 and styrene (see scheme). The resulting copolymers 2 have unprecedented phosphine-containing backbones with phosphorus compositions that vary depending on the monomer ratios. These novel functional hybrid inorganic–organic macromolecules are used as polymeric supports for the Pd-catalyzed Suzuki coupling. VAZO=1,1′-azobis(cyclohexanecarbonitrile).
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Tsang et al. (2004) studied this question.
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