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The A 1Σ+u state of 7Li2 has been studied using all optical triple resonance spectroscopy. Vibrational levels v=27–62 and rotational levels ranging from J=0 to 27 have been observed. This represents a region between previous data from single photon experiments and new data from cold atom photoassociative spectroscopy. Our data was fit to a Dunham expansion and the resulting molecular constants reproduce most observed energies to within 0.050 cm−1. A Rydberg–Klein–Rees potential curve has also been constructed and the calculated eigenvalues are in good agreement with observed energies.
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Urbanski et al. (1996) studied this question.
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