Electrospinning Preparation of Nanostructured g-C3N4/BiVO4 Composite Films with an Enhanced Photoelectrochemical Performance

Nanostructured g-C 3 N 4 /BiVO 4 composite films with an enhanced photoelectrochemical (PEC) performance have been fabricated via the facile electrospinning technique. The g-C 3 N 4 nanosheets can not only form heterojunctions with BiVO 4 but also prevent the agglomeration of BiVO 4, helping the formation of nanostructures. The as-prepared g-C 3 N 4 /BiVO 4 films exhibit good coverage and stability. The PEC performance of the g-C 3 N 4 /BiVO 4 films is much more enhanced compared with that for individual BiVO 4 films because of the enhanced electron–hole separation. The photocurrent density is 0.44 mA/cm 2 for g-C 3 N 4 /BiVO 4 films at 0.56 V in the linear sweep current–voltage test, over 10 times higher than that of individual BiVO 4 films (0.18 mA/cm 2 ). The effects of the preparation conditions including the g-C 3 N 4 content, collector temperature, calcination temperature, and electrospinning time on the PEC performance were investigated, and the reasons for the effects were proposed. The optimal preparation condition was with 3.9 wt % g-C 3 N 4 content in the electrospinning precursor, 185 °C collector temperature, 450 °C calcination temperature, and 40 min electrospinning time. The excellent PEC performance and the facile preparation method suggest that the g-C 3 N 4 /BiVO 4 films are good candidates in energy and environmental remediation area.