The effect of the halomethanes CC12F2, CH2Cl2, CHCl3 and CCl4 on the production of ozone using oxygen feed gas in a negative corona discharge has been investigated experimentally. The fall in the product ozone yield was found to increase with increasing number of halogen atoms substituted in methane molecule. A detailed description of the role of these halogen species in the chemistry of the discharge is given.
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Skalný et al. (2002) studied this question.
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