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Thermolyses of pentacoordinate 1,2-oxasiletanides with or without a neopentyl group at the 3-position in the presence of a proton source afforded the corresponding olefin and/or alcohol, indicating that they are the intermediates of both the Peterson reaction and homo-Brook rearrangement which are two possible modes in the reaction of β-hydroxyalkylsilanes with bases.
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Naganuma et al. (1999) studied this question.
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