This review provides a brief introduction to the Langmuir‐Blodgett (LB) technique and to the utilization of ultrathin films in the fields of electronics and optics. The electrical and nonlinear optical properties of the Langmuir‐Blodgett monolayer and multilayers of organoruthenium complexes, ferrocene derivatives, metal(4,5‐dimercapto‐1, 3‐dithiol‐2‐dithiolene)2 complexes, metallophthalocyanines, metalloporphyrins, metal(dibenzotetra‐aza[14]annulene)s and siloxane polymers are presented. Possible applications of organometallic LB films in sensors, electroluminescence and electrochromic devices, optical switches, solar cells, infrared detectors and harmonic generators are discussed.
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Nalwa et al. (1992) studied this question.
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