Core–corona composites were prepared by incorporating a hydrophilic polyoxometalate (POM) into poly(styrene-b-4-vinyl-N-methylpyridinium iodide) matrices in acidic aqueous solution (see scheme). On dispersal in toluene they self-assemble into micellar and vesicular morphologies (see TEM images), which can be controlled by means of the weight fraction of POM.
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Bu et al. (2009) studied this question.
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