The reported Mn(II)-azide system is the first example of a two-dimensional homometallic ferrimagnet, in which the magnetic properties are due exclusively to topological reasons related with the coordination mode of the bridging ligands; it is also the first case in which a system of this kind exhibits long range order comparable to the classical heterospin ferrimagnets.
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Escuer et al. (2004) studied this question.
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