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Measurements on the thermal dissociation of gaseous and the reaction of gaseous with excess germanium have been made by observing the dependence of the total pressure on temperature for the corresponding closed systems at constant volume. The dependence of equilibrium constant on temperature is given for the reactions and Average heats of reaction and entropy changes are deduced for the temperature range 600°–1200°K.
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R. F. Lever (1963) studied this question.
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