Structural Characterization of the Redox Behavior in Copper-Exchanged Sodium Zeolite Y by High-Resolution Powder Neutron Diffraction

The results of structural refinements on high-resolution powder neutron diffraction data for copper(II)- and copper(I)-exchanged zeolite Y and for the parent sodium zeolite Y, with composition Na 62 Si 128 Al 64 O 384, are presented. Rietveld refinement of ambient-temperature data shows that the Cu(I) and Cu(II) cations are located on different sites in the two materials and that the structures differ considerably from that adopted by NaY. In Cu II Y, with composition Cu 33 Na 12 Si 130 Al 62 O 384, the copper cations are located on the I A ‘, I B ‘, and II‘ sites with occupancies of 0.552(4), 0.145(7), and 0.162(8), respectively, while some sodium, 0.36(2), remains on site II. For Cu I Y, there is a redistribution of the cations on sites I A ‘, I B ‘, II‘, and II to 0.39(2), 0.21(1), 0.24(1), and 0.18(2), respectively. In both zeolites, site I is vacant. The high-quality diffraction data provide direct evidence of structural changes associated with the redox behavior of the zeolite, including distortion of the framework and the location of charge-balancing species.