A microwave-assisted Kochetkov reaction (a) has been used on different reducing carbohydrates to obtain glycosylamines and then N-iminoglycosylamidines without purification. These glycoconjugates were then used to construct microarrays to test known carbohydrate–protein interactions. This method streamlines efforts required to functionalize carbohydrates for construction of arrays.
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Brun et al. (2006) studied this question.
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