Radiative lifetimes of AlH(AlD) A1Π have been measured in a hollow cathode discharge by dye laser excitation, in ns: Predissociated rotational levels lifetimes are given and used to precise the shape of the hill of the A1Π potential energy curve crossed by tunnel effect. The AlH dissociation energies are found: for A1Π, De(eV) =0.24±0.01 and for X1Σ+, De(eV) =3.17±0.01. The normal levels lifetimes variation with v′ is attributed to a configuration mixing in A1Π.
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Baltayan et al. (1979) studied this question.
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