Amperometric detection in high performance liquid chromatography was applied for the determination of carbohydrates in human serum. Remarkable difference of mannose content was observed for serum in disorder states compared with normal subjects. Clinical interest was suggested by an unsusceptibility of mannose to influence of meal and a significant correlation of mannose to glucose content. The selectivity involved in the method and the stability of a working electrode were excellent by virtue of a low applied potential.
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Watanabe et al. (1984) studied this question.