The α‐chloronitroso mannose derivative 1 undergoes ene reactions with alkenes 2 to yield nitrone hydrochlorides 3 which may be hydrolyzed to allylic hydroxylamines. The enophilic reactivity of 1 is much higher than that of other α‐chloronitroso compounds. The reaction seems to be highly diastereoselective.
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Kreße et al. (1986) studied this question.
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