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The review article provides a personal overview on the development and application in enantioselective synthesis of nonracemic chiral homoenolate reagents, based on allylic N,N-dialkylcarbamates and the ideas behind it. Further, the impact of these results, concerning stereoselective deprotonation, mainly under the influence of the chiral diamine (-)-sparteine, for the generation of a wide range of chiral building blocks is briefly presented.
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Dieter Hoppe (2008) studied this question.
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