The search for catalysts for olefin polymerization has brought complexes into the limelight that contain anionic 1,1′-ferrocenedi(amido) chelate ligands. The stabilization of cationic titanium centers by such a chelate ligand may lead to the formation of a dative Fe→Ti heterodimetallic bond, as in the cation of the salt 1.
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Max Herberhold (2002) studied this question.
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