1,2-Bis(formylamino)benzene was crystallized from methanol as chiral crystals belonging to space group P212121. Both of the formylamide moieties of the compound are almost planar and the configurations are Z. They are located on the same side of the central benzene ring (syn conformation) and tilted in the same direction.
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Azumaya et al. (2003) studied this question.
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