A helping hand: The assisted fixation of CO2 and its transformation into a carbonato ligand has been achieved using a di(silyl)cyclopentadienyl titanium(IV) complex. In the presence of water and under air, a dinuclear carbonato titanium(III) complex (see picture) is formed. Theoretical investigations into the electronic properties of this titanium(III) complex explain its high stability and diamagnetism.
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Santamaría et al. (2005) studied this question.
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