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The chlorination of a pristine C102 fullerene separated by HPLC from fullerene soot afforded crystals of C102Cl20 with a non-IPR (IPR = isolated pentagon rule) cage containing two pairs of fused pentagons; structural reconstruction of a two-step Stone-Wales rearrangement revealed the starting IPR isomer (no. 19) of C102.
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Yang et al. (2013) studied this question.
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