Halogenation of higher fullerene mixtures or their perfluoroalkylation with RFI followed by HPLC separation of RF derivatives and subsequent synchrotron X-ray crystallographic study made it possible to confirm cage connectivities of higher fullerenes and, in addition, to receive information concerning their reactivity in radical addition reactions. The data obtained are compared with theoretical predictions for higher fullerenes. Addition patterns of higher fullerene derivatives are discussed. Skeletal rearrangement of the D 2-C76 cage during chlorination has been observed for the first time.
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Tamm et al. (2009) studied this question.
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