Solvent-mediated vibrational relaxation in UV pump–probe experiments has been studied using cycloheptatriene (CHT) and its perdeuterated counterpart (CHTd8) as model systems. Transient spectra containing absolute ε(t) values are obtained by a modified Sulzer–Wieland ansatz and a global fit function for vibrational relaxation is proposed.
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Schalk et al. (2009) studied this question.
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