The concepts of ``bond dissociation energy'' and ``average bond energy'' are analyzed. A mathematical treatment is suggested which makes it possible in principle to distribute the energy of atomization among the various bonds of the molecule. The relationship between the ``bond dissociation energy,'' ``average bond energy,'' and ``reorganization energy'' is examined in the light of various molecular force fields.
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Szwarc et al. (1950) studied this question.
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